Elastomeric covered roller having a thermally sprayed bonding material

ABSTRACT

A elastomer-covered roller ( 10 ) is provided with an improved bond coating for bonding the elastomeric cover ( 14 ) to the core ( 11 ). At least one layer of material ( 15 ) is thermally sprayed on the core to form a rough surface having a roughness from 400 microinches R a  to 2000 microinches R a  or greater. In a further improvement a denser, less porous layer ( 17 ) may be applied next to the core to protect the core from corrosion, followed by a less dense layer ( 19 ) applied to the first layer and having a similarly rough surface ( 20 ) for good mechanical bonding.

CROSS REFERENCE TO RELATED APPLICATION

This is a division of U.S. appl. Ser. No. 09/570,250 filed May 12, 2000,now U.S. patent No. 6,394,944.

TECHNICAL FIELD

The invention relates to the manufacture of elastomeric-covered rollers.

DESCRIPTION OF THE BACKGROUND ART

Rollers with covers of elastomeric material are used in a wide varietyof industrial applications. One process is a plastic film manufacturingprocess known as cast film extrusion. Films of thermoplastic polymerssuch as polyvinylchloride and polycarbonate are made by this process.The most popular polymers made by this process are polyethylene andpolypropylene.

In a typical application, molten polymer from an extruder is droppedinto a nip formed between a chrome-plated steel roller and anelastomer-covered steel roller. One common type of elastomer used inthis application is silicone rubber, although Hypalon™, available fromDu Pont, and other polymer materials can also be used. The chrome-platedsteel roller and the elastomer-covered roller are normally water cooled,or otherwise chilled, since the molten plastic may be at a temperatureof several hundred degrees Fahrenheit. The chrome-plated roller quicklychills the plastic below its melting point and the nip formed with theelastomer-covered roller determines the gauge (thickness) and thesurface finish of the film. The flexibility of the rubber coveringcompensates for minor machine misalignment and other variables, andprovides a wider nip than two hard surfaced rollers.

Silicone rubber is a material that may be used as the cover in theelastomer-covered roller described for the above application. Siliconerubber is, however, a material that is difficult to bond to a metalroller core on a consistent basis. It is also difficult to maintain thebond in applications where the roller is used at high temperature andhigh pressure. In some cases, the silicone rubber may peel cleanly offthe metal core without leaving any residue of rubber, indicating a lossof bonding. Loss of bonding in one area requires that theelastomer-covered roller be replaced.

The fact that the elastomer peels cleanly from the metal core surface,leaving little if any rubber residue on the core, indicates that thestrength of the rubber/metal bond is weaker than that of the rubberitself. An adequate rubber/metal bond is generally considered to be onethat is greater than the strength of the rubber. Bond interfaces thatare initially adequate when formed can deteriorate relatively quicklyunder thermal or mechanical stresses in an actual field application.This is especially true for elastomers that are either inconsistent intheir bonding properties or do not form particularly strong bonds tometals. Included in this group are silicone, EPDM(ethylene-propylene-diene-monomer), and urethane elastomers. Currentmethods of core surface preparation, prior to elastomeric bonding,include disc or belt sanding, shot blasting, sand blasting, and gritblasting. A cleanly tooled surface is not generally rough enough topromote a strong rubber to metal bond. These methods attempt to furtherclean the core surface of all oxides and contaminants, after solventshave been used to remove greases and oils, while increasing the surfacearea available for bonding. After the metal surface has been prepared,one or more chemical bonding agents are applied. These materials arespecific to the type of elastomer being used and are well known in theindustry. The total thickness of these bonding agents is frequently onthe order of one mil.

The best surfaces for bonding that can be produced are by grit or shotblasting. The maximum roughness value that can be consistently achieved,with adequate process controls, is in the 500 microinches R_(a) range,but typical values for most processes are lower. Blasting increases thesurface roughness and surface area but the surface profile is relativelysimple, just peaks and valleys. The best grit blasted surfacepreparation will produce an adequate bond to the elastomer cover andwill not peel cleanly at the rubber/metal bond interface under normaltemperature and pressure stresses. However, the amount of rubber residueleft on the core is relatively small.

A roller under mechanical stress, such as a silicone covered roller forexample, has a concentration of stress at the rubber to metal interface,because of the vast difference in the compression modulus values betweenthe elastomer and the core. This stress riser tends to shear the rubberaway from the core at the bond interface.

An improved bonding surface is needed for elastomers that are weakly orinconsistently bonded, especially if the covered rollers are exposed tohigh temperature or pressures, or high moisture conditions. The bondingsurface must provide a high surface area and surface roughness and yetbe easily and consistently produced. A very high surface roughness willalso diffuse the stress riser at the bond interface improving thelongevity of the rubber to metal bond.

Polyurethane is another material that can be used for the elastomericcover in the present invention. For bonding polyurethane to supportinglayers, primary reliance has been placed on chemical bonding, to beassisted by mechanical bonding. As with silicone-based materials, thelimit of surface roughness available with current methods of mechanicalbonding is about 500 microinches R_(a).

In addition, water vapor easily permeates through either a siliconerubber layer or a polyurethane layer, and corrosion may occur at thebond line due to the collection of water vapor there. Moisture willmigrate into the outer roller cover if the roller is either chilled orexposed to water in the application. It would be beneficial to provide abond coat or layer that is resistant to such corrosion, as well as oneproviding a stronger mechanical bond.

SUMMARY OF THE INVENTION

The invention concerns a method of making a roller that includesthermally spraying a bond coat to substantially cover a portion of thecore on which an elastomeric layer is to be bonded and in which the bondcoat provides a surface roughness to assure a strong mechanical bond tothe elastomeric layer.

The invention also concerns a roller resulting from the method andhaving a bond coat with a surface roughness that provides a strongmechanical bond to an elastomeric layer.

The bond coat comprises a thermally sprayed material selected from agroup of materials consisting of metals, metal alloys, ceramics andcermets.

In the prior art, core surfaces were prepared by sanding or blasting themetal core prior to the application of chemical bonding agents. Thesemethods do not always produce the desired level of mechanical bonding.Thermal spraying has been known in the manufacture of ceramic coveredrollers, but has not heretofore been applied to bond elastomeric layersto a metal core.

The invention provides improved constructions of elastomeric rollers.These elastomers include silicone, EPDM(ethylene-propylene-diene-monomer), urethane elastomers and othersynthetic or natural rubber elastomers. Although the invention isdescribed in examples in which the elastomeric layer is the outer layer,it would also be possible to add layers outside the elastomeric layer.

The invention may be practiced in further aspects by providing atwo-layer bond coat in which the material of the base layer is denserfor protection against corrosion and the top layer is coarser for abetter bonding. Other objects and advantages of the invention, besidesthose discussed above, will be apparent to those of ordinary skill inthe art from the description of the preferred embodiments which follow.In the description, reference is made to the accompanying drawings,which form a part hereof, and which illustrate examples of theinvention. Such examples, however, are not exhaustive of the variousembodiments of the invention, and therefore, reference is made to theclaims which follow the description for determining the scope of theinvention.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a perspective view of a roller incorporating the presentinvention;

FIG. 2 is a detail sectional view of a first embodiment of the presentinvention taken in a plane indicated by line 2—2 in FIG. 1; and

FIG. 3 is a detail sectional view of a second embodiment of the presentinvention taken in the same plane as FIG. 2.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

Referring to FIG. 1, an elastomer covered roller 10 of the presentinvention includes a core 11, with journal shafts 12, 13 extending fromopposite ends of the core 11, and a layer 14 of elastomeric material, inthis example, silicone rubber, which in this example forms the outercover of the roller 10. The core 11 may be made of metal, such as steel,or it may be made of a fiber-reinforced resinous composite material asdisclosed in Carlson, U.S. Pat. No. 5,256,459, issued Oct. 26, 1993.

The elastomeric material may be applied using conventional and knownmethods. Silicone rubber can be applied using methods such as liquidcasting, various forms of extrusion, or by wrapping the core withcalendered sheets of rubber. Urethanes may be applied by liquid castinginto a mold or by a liquid ribbon process described in U.S. Pat. No.5,206,992 and U.S. Pat. No. 5,415,612 assigned to the assignee of thepresent invention.

As seen in more detail in FIG. 2, a layer 15 of thermally sprayedmaterial is applied to the core 11 as a bonding surface for the covermaterial 14. This layer 15 is typically composed of a ceramic, cermet,metal, or alloy. The preferred materials are relatively high inporosity, while retaining structural integrity. These materials alsoprovide rough, complex surfaces after spraying and are easily bonded torubber. Unlike the simple surface profiles produced by sanding andblasting, thermally sprayed surfaces are more complex and have manysurface features that can trap the rubber to form an interlocking bond.Layers produced by the wire arc process are somewhat more complex thansanded or blasted surfaces. Layers produced by the application ofthermally sprayed powders are even more complex. Bonding surfacesproduced by thermally sprayed powders are used for bonding ceramics tometals, a process which is entirely mechanical. When it is desired tobond an elastomer to a metal or alloy core, the bond is produced by acombination of chemical bonding and mechanical bonding. In that case, itis typical to apply bonding agents and primers over the thermallysprayed bond coat. This allows the elastomer to become chemically bondedto the thermally sprayed core.

The surface roughness for robust mechanical bonding of silicone rubberor similar materials is at least 400 microinches R_(a) or more, althougha surface roughness of only 200 microinches Ra will provide a bondadequate for many applications (R_(a) denotes average roughness underASME standards and numerical measure in units of microinches.) With thethermally sprayed material, surfaces up to 2000 microinches R_(a) havebeen successfully tested and provide a superior mechanical bond.Ceramics typically provide a surface roughness of less than 300microinches R_(a), if used alone, and do not provide bonding surfaceswhich are as robust as materials providing rougher surfaces. Alumina,alumina/titania, and zirconia ceramics can be used in combination withmetals to increase the texture of bonding surface 16.

The preferred material is a metal or alloy, in wire or rod form, appliedby a thermal spraying step. The resulting roughness of the surface 16 isin a range from approximately 500 microinches R_(a) to approximately2000 microinches R_(a). The maximum surface roughness of a thermallysprayed coating that can currently be produced is in the 2000 Ra range.The roughness of the surface 16, as well as the thickness of the layers11, 14, and 15 have been exaggerated in FIGS. 2 and 3. This roughnesslevel greatly improves the mechanical bond strength of therubber-to-metal interface. One example is Sulzer Metco #2 wire, which isa Nr. 420-type (400 series) stainless steel alloy. 300 Series alloys canalso be used. This material can be sprayed at high rates (>25 pounds perhour), is low in cost, and can be applied in a series of thinner coatinglayers or in a very thick layer. This material also bonds well to mostelastomers. It provides the steel roller core 11 with a measure ofcorrosion protection even though it is somewhat porous. Sulzer Metco #2wire for example, applied by the wire arc thermal spray process, can beapplied in practical layers up to at least 250 mils in thickness.Thicker layers can be applied but may not be cost effective compared toother means to increase the core diameter. One of the problems withconventional rubber roller re-covering is that part of the core surfaceis frequently machined off to provide a clean bonding surface. Over aperiod of time, the core diameter becomes too small to use or the rubbercover thickness increases excessively. With a layer of thermal spraymaterial on the core, it is no longer necessary to remove part of thecore surface to prepare the core surface for recovering. Part or all ofthe thermal spray layer can easily be machined off and replaced. Also, afew mils of the thermal spray layer can be ground off to clean thesurface, followed by a thin application of the same thermal spraymaterial. A new layer of thermal spray material is easily bonded to anold one. The materials bond well together, as long as the sprayedsurface is clean and free from grease and oil. The addition of athermally sprayed layer can be used to help control the outer diameterof the core.

Other thermally sprayed materials and methods have also proven toprovide a superior bonding surface according to the present invention.Eutectic 18923 and Sulzer Metco 43C powders, which are both 80/20 alloysof nickel and chromium metals can be used. These materials, as well asany corrosion resistant thermal spray material, 300 series and 400series stainless steels, nickel chrome alloys, and other nickel-basedalloys, provide both corrosion protection of the core and a suitablebonding surface for elastomers. The surface profiles of most thermallysprayed metals and alloys are very similar for a given particle size inthe starting material. The roughness of the surface formed by a layer ofEutectic 18923 is typically 400 microinches R_(a) while the Sulzer Metco43C provides a surface roughness of about 700 microinches R_(a), ifsprayed with an oxygen-fuel gun device such as the Eutectic Teradyne3000 or Sulzer Metco 6P. The particle size of the 43C is larger than the18923 which accounts for the R_(a) difference. A thickness of thecoating or layer 15 of these materials in a range from 3 to 20 mils hasprovided strong and uniform bonds to an outer layer 14 of siliconerubber although thinner layers can be used as long as the thickness ofthe coating can be made uniform.

Although the Eutectic 18923 and 43C coatings do not provide as rough abonding surface as the Sulzer Metco #2 wire arc coatings, thesematerials still provide a bond interface having properties superior to agrit-blasted surface having a similar R_(a). Compared to grit blasting,the thermally sprayed surface is more easily and consistently formed aswell.

Under magnification, the #2 wire arc surface appears to be a series ofmountains and valleys. It is more complex than a sanded or blastedsurface. The thermally sprayed powder surfaces produce a more complexsurface that looks like a sintered metal under a microscope. Theelastomer can actually diffuse into the thermal spray coating to thedepth of a few mils.

The roughest surfaces, approximately 1000 microinches Ra or greater,provide the best diffusion of stress concentrations at the bondinginterface or boundary 16. The bond interface 16 becomes thicker and morediffused.

If the metal or alloy of the somewhat porous thermal spray layer isdissimilar from the core material, it may be possible to have galvaniccorrosion at the interface between the roller core 11 and the permeablelayer. The two metals and the water (which will contain someelectrolytes) will form a battery (in localized areas) and corrosionwill occur at the anode, usually the (steel) core. Even though the coreand thermal sprayed layer should be in solid electrical contact (i.e. ashort circuit) and should not form a battery, the oxides present in thethermal spray coating can act as an insulator at the core interfacedepending on the material sprayed, the spray equipment, and the sprayparameters.

In order to avoid the possibility of corrosion, the thermal spray layercan be made in two layers of differing porosity levels as illustrated inFIG. 3. The first body of material 17 and the second body of material 19should comprise the same metal or alloy material in order to avoidgalvanic corrosion between the sprayed layers. The first body ofmaterial 17 can be applied by plasma spraying or HVOF (high velocityoxy-fuel) spraying or low velocity flame spraying to produce arelatively dense, pore-free coating. It should be understood that thecoating 17 can be the result of several passes of the spray gun whichprovides several thinner coatings that are merged into a thickercoating. The second body of material 19 can be then applied by the wirearc step to provide a coarse, porous coating, using the techniquesdescribed above. A suitable thickness for the dense body of material 17is in the range of 3 to 60 mils, but is more preferably in the range of10 to 20 mils.

The second body of material 19 can then be applied in a second layerwithout any additional surface preparation. Excellent bonding betweenlayers would be achieved due to the resulting roughness of surface 18 ofthe thermally sprayed material 17.

In the case of thermally sprayed powder coatings used as the only layer19, a layer of Eutectic 18923 (or other nickel based corrosion resistantalloys or stainless steels), 3 mils or more in thickness, generallyprovides adequate corrosion protection of the core in lieu of the layer17 of dense metal or alloy material.

The above has been a description of the detailed, preferred embodimentsof the apparatus of the present invention. Various modifications to thedetails which are described above, which will be apparent to those ofordinary skill in the art, are included within the scope of theinvention, as will become apparent from the following claims.

We claim:
 1. A roller comprising: a roller core; a bond coat bonded tothe core to provide an outer surface roughness; a coat of elastomericmaterial bonded to the bond coat; and wherein said bond coat comprises athermally sprayed material selected from a group of materials consistingof metals, metal alloys, ceramics and cermets having an outer surfaceroughness in a range from 401 microinches R_(a) to approximately 2000microinches R_(a); and wherein the elastomeric material is eithersilicone rubber or a natural rubber or a synthetic rubber or a urethaneelastomer.
 2. The roller of claim 1, wherein the bond coat material iseither a metal wire, a rod or a powder material.
 3. The roller of claim1, wherein the bond coat comprises a plurality of coating layers.
 4. Theroller of claim 1, wherein the core is made of metal.
 5. The roller ofclaim 1, wherein the thickness of the bond coat is in a range from 2mils to 250 mils inclusive.
 6. The roller of claim 1, wherein the bondcoat further comprises a single layer having a thickness of at least 2mils.
 7. The roller of claim 1, wherein the core is made of afiber-reinforced material.
 8. The roller of claim, 1 wherein the bondcoat is a 300 series or 400 series stainless steel alloy.
 9. The rollerof claim 1, wherein the bond coat is a nickel-chromium alloy.
 10. Theroller of claim 1, wherein the bond coat is a nickel-based alloy. 11.The roller of claim 1, wherein the elastomer is applied by casting,extrusion, or wrapping with calendared rubber sheets.
 12. The roller ofclaim 1, wherein the rubber covering material comprises a natural orsynthetic elastomer.
 13. The roller of claim 1, wherein mechanical andchemical bonding agents are disposed in the roller to assist bondingbetween the thermal spray bond coat and the elastomeric coveringmaterial.
 14. The roller of claim 1, wherein the thermally sprayed bondlayer is disposed over an existing thermally sprayed bond layer that hasbeen cleaned of grease, oil, and contaminant.
 15. The roller of claim 1,wherein the core diameter is maintained at a specified value by theadjustment of thickness of the thermally sprayed bond layer.
 16. Aroller comprising: roller core; a bond coat bonded to the core toprovide an outer surface roughness; a coat of elastomeric materialbonded to the bond coat; and wherein said bond coat comprises athermally sprayed material selected from a group of materials consistingof metals, metal alloys,, ceramics and cermets; a layer of elastomericmaterial disposed over the bond coat; and wherein the bond coat furthercomprises a first layer and a second layer, the first layer having agreater density and less porosity than the second layer so as to resistcorrosion of the core.
 17. The roller of claim 16, wherein the bond coathas a surface roughness in a range from 401 microinches R_(a) toapproximately 2000 microinches R_(a).
 18. The roller of claim 16,wherein the second layer is coarser than the first layer for the purposeof assisting mechanical bonding to the elastomeric layer.
 19. The rollerof claim 16, wherein the elastomeric material is either silicone rubberor a urethane elastomer or EDPM rubber.